Heat the oven to 450 with a rack in the middle position. Line a rimmed baking sheet with parchment paper or aluminum foil. In a small bowl, whisk the oil,, 2 1/2 TBSP of mustard, the vinegar, honey, garlic, 1 tsp salt, and 1/4 tsp pepper until creamy.Measure 1/4 cup of mixture and set aside.
Place the cauliflower on the cooking sheet and brush the surface with the remaining mustard-oil mixture. Roast the cauliflower until deeply browned and a skewer inserted all the way through the head and into the core meets just a little resistance, about 40 to 55 minutes.
While the cauliflower roasts, in a small bowl bowl, toss together the crumbled feta and chopped parsley. When the cauliflower is ready, remove the baking sheet from the oven. Brush the remaining 1 1/2 TBSP mustard over the surface of the cauliflower, then pat on the feta mixture, pressing so that it adhere. Return to the oven and continue to roast until the feta begins to melt, 5 to 8 minutes.
Transfer the cauliflower to a cutting board using a wide metal spatula, then cut into 4 wedges. Serve with lemon wedges and the reserved mustard-oil mixture.